Synthesis and development of novel tetra-aza catalyst platforms
| Author(s) | Fitzsimons, Matthew | |
| Date Accessioned | 2017-03-20T12:25:12Z | |
| Date Available | 2017-03-20T12:25:12Z | |
| Publication Date | 2016 | |
| Abstract | Potential tetra-aza catalytic platforms have been synthesized and there electronic structures investigated through various methods. A tris (pentafluorophenyl) phlorin derivative was bound to a phosphorous(V) central atom. The complex was characterized with electronic spectroscopy, cyclic voltammetry, differential pulse voltammetry, and 1H NMR spectroscopy. The complex was compared with an analogous phosphorous corrole. A novel bis(imino) ligand with a dipyrromethane spacer was developed and bound to several metal centers, including Ni(II) and Zn(II). These complexes and the free-base ligand were characterized with a variety of techniques and structures were confirmed with X-ray crystallography. | en_US |
| Advisor | Rosenthal, Joel | |
| Degree | M.S. | |
| Department | University of Delaware, Department of Chemistry and Biochemistry | |
| Unique Identifier | 976432229 | |
| URL | http://udspace.udel.edu/handle/19716/21144 | |
| Publisher | University of Delaware | en_US |
| URI | https://search.proquest.com/docview/1840893083?accountid=10457 | |
| Title | Synthesis and development of novel tetra-aza catalyst platforms | en_US |
| Type | Thesis | en_US |